## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Complexation of Titanium Alkoxides withCis-2-butene-1,4-diol and Hydrolysis of Their Products
β Scribed by Asgar Kayan
- Book ID
- 110429431
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 244 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1053-0495
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## Abstract Complexation reactions of titanium tetraethoxide [Ti(OEt)~4~] and titanium tetraβ__n__βbutoxide [Ti(OBu^__n__^)~4~] with 3βpentenoic acid (PA) and allylacetoacetate (AAA), in a 1 : 1__M__ ratio, were studied in ethanol solution at room temperature. ^13^CβNMR and FTIR spectra showed that
A highly efficient and stereoselective technique for additions to syn-Ξ²-alkyl-Ξ²-hydroxy-Ξ±-methyl ketones is now available. The methodology is based on the conversion of the starting material into a trichlorotitanium alkoxide derivative, which is able to assume a stable cyclic arrangement exhibiting