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Complexation of phthalides and substituted 3-benzylidene phthalides with Cr(CO)6

✍ Scribed by Peter Hrnčiar; Peter Ertl; Pavol Hrnčiar; Štefan Toma

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 491 KB
Volume: 464
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(94)87010-1

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## The reaction of Cr(CO)j-complexed chloroarenes with HCO$H:, and NaOCH3 in the presence qf a catalytic amount of PdC&PPh3)2 gives esters in good yieldr provided that the arene is substituted by an electron-&Wing group, whereas the presence of an electron-withdrawing substituent on the aromatic r