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Complexation of Phosphine Ligands with Peracetylated β-Cyclodextrin in Supercritical Carbon Dioxide: Spectroscopic Determination of Equilibrium Constants

✍ Scribed by Galia, Alessandro; Navarre, Edward C.; Scialdone, Onofrio; Ferreira, Michel; Filardo, Giuseppe; Tilloy, Sebastien; Monflier, Eric


Book ID
126072206
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
133 KB
Volume
111
Category
Article
ISSN
0022-3654

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Hydroformylation of 1-Octene in Supercri
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## Abstract The presence of peracetylated β‐cyclodextrin in the reaction medium allowed for an increase in the solubility of rhodium species modified by alkyl P‐donor ligands in the catalytic hydroformylation of 1‐octene in supercritical carbon dioxide. These results were explained by considering a