Complexation of PhAsCH2 and Synthesis of a Novel RhAs3-Metallaheterocycle
β Scribed by Prof. Dr. Helmut Werner; Wilfried Paul; Ralf Zolk
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 266 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0044-8249
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π SIMILAR VOLUMES
## Reactions of PhAsCl 2 with BrMg(CH 2 ) n MgBr (n = 4 or 5) in THF gave phenylarsacycloalkanes as colourless oily liquids which could be distilled under vacuum. Treatment of PhAs C (CH 2 ) n with MCl 2 (RCN) 2 (M = Pd or Pt; R = Ph or Me) afforded mononuclear complexes, [MCl 2 {PhAs C (CH 2 ) n
A series of linear primary polyamines H 2 N-CH 2 -(CH-NH 2 ) n -was established by potentiometric titrations and was compared with previous reports. The crystal structure of the CH 2 -NH 2 (1 Υ n Υ 3) was prepared from the corresponding polyalcohols. The polyamines were isolated as HCl adducts Cu co