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Complexation of Palladium(II) Acetate and Acetylacetonate with Mono- and Bidentate Phosphine Ligands

✍ Scribed by G. P. Belov; Z. M. Dzhabiyeva; V. A. Fastovets

Book ID
110418625
Publisher
SP MAIK Nauka/Interperiodica
Year
2003
Tongue
English
Weight
51 KB
Volume
29
Category
Article
ISSN
1070-3284

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The synthesis and properties of cationic complexes of general formula [ML2{CH2(Ph2PE)2}]BF4, where M = Pd H and Rh n, L2 = q3-MeC3H4, {P(O)(OR)z}EH (R = Me, Et), COD, (CO)z, (CO)PPh 3 and E = S, Se are described. The methylene proton of the coordinated phosphine sulphide or selenide ligands react wi