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Complexation of Ni(II) and Co(II) with 1,4-Dioxa-7,10,13-triazacyclopentadecane ( L ). Crystal Structure of [NiLCl][NiL(H 2 O)](ClO 4 ) 3 and Macrocycle-Induced Dioxygen Binding

✍ Scribed by Bazzicalupi, Carla; Bencini, Andrea; Berni, Emanuela; Bianchi, Antonio; Giorgi, Claudia; Paoletti, Piero; Valtancoli, Barbara


Book ID
127333110
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
53 KB
Volume
39
Category
Article
ISSN
0888-5885

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One-dimensional structures of nickel(II)
✍ M John Plater; Mark R.St J Foreman; Thomas Gelbrich; Michael B Hursthouse πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 133 KB

Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a