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Complexation of neutral guest molecules by synthetic macroheterocyclic hosts

✍ Scribed by David N. Reinhoudt; Jr Herman J. Den Hertog

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
421 KB
Volume
97
Category
Article
ISSN
0037-9646

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Highly preorganized his-thiourea receptors based on a xanthene spacer selectively (HzP04-> CH3COO-> Cl-) bind dihydrogenphosphate via multitopic hydrogen bonding, giving stronger complexes with H2PO4. than any synthetic neutral receptor known so far. The high complexation strengths are rationalized