Complexation and Separation of Amines, Amino Acids, and Peptides by Functionalized Calix[n]arenes
✍ Scribed by Lucia Mutihac; Hans-Jürgen Buschmann; Radu-Cristian Mutihac; Eckhard Schollmeyer
- Book ID
- 106388505
- Publisher
- Springer Netherlands
- Year
- 2005
- Tongue
- English
- Weight
- 368 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0923-0750
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## Abstract A general method has been developed for the preparation of bis(syn‐proximally) functionalized calix[4]arenes (6, 8–10). Starting from __p‐tert__‐butylcalix[4]arene 1a and calix[4]arene 1b syn‐proximally __dialkylated__ calix[4]arenes 2a and 2b, 4, and 5, respectively, were obtained by t
MD simulations using a combination of AM1 and AMBER are performed to elucidate the origin of complexation between fullerenes and calix(n]arenes (n = 4,6,8). Gnly calix[ó]arenes and calix[8]arenes are suitable for complex formation. By introducing bcnayl substitutents on the upper rim of the calixare