The kinetics of oxidation of cis-[Cr III (phen) 2 (H 2 O) 2 ] 3+ (phen = 1,10-phenanthroline) by IO - 4 has been studied in aqueous acidic solutions. In the presence of a vast excess of [IO - 4 ], the reaction is first order in the chromium(III) complex concentration. The pseudo-firstorder rate cons
Complexation and electronic spectra of neodymium(III)-amino acid-1,10-phenanthroline systems in aqueous solution
β Scribed by Wu Yang; Jinzhang Gao; Jingwan Kang; Weidong Yang
- Publisher
- Springer US
- Year
- 1997
- Tongue
- English
- Weight
- 336 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0095-9782
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π SIMILAR VOLUMES
## Abstract The kinetics of oxidation of several substituted quinols by a series of Tris(1,10βphenanthroline)iron(III) complexes has been investigated with a stoppedβflow technique at 6.0 and 20.0Β°C. The reactions were found to be first order on both reactants and independent of acidity. The second
The natural decay of Fe(phen)33 Β§ where no Ce w is employed for scavenging the side reaction product, Fe(phen)~ +, is now treated as a complex reaction involving two parallel processes, and the experimental kinetics are consistent with the rate laws derived from a mechanism that simultaneously expla