Complex rate law for the cerium(IV) oxidation of glycolic acid in the medium HClO4–Na2SO4–NaClO4

Kinetics of the redox reactions between

Kinetics of the redox reactions between ceric sulfate and lactic and atrolactic acids in the medium HClO4-Na2SO4-NaClO4

✍ Giuseppe Calvaruso; F. Paolo Cavasino; Carmelo Sbriziolo 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 English ⚖ 483 KB

The kinetics of the oxidation of lactic and atrolactic acids by ceric sulfate have been studied in the medium HC10,-Na,S04-NaC104 at 25.0"C and ionic strength 2.0 mol dm-3 over a wide range of organic substrate (HL), hydrogen and bisulfate ion concentrations. The redox reactions proceed significantl