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Complex Macromolecular Architectures by Combining TEMPO Living Free Radical and Anionic Polymerization

✍ Scribed by Tsoukatos, Thodoris; Pispas, Stergios; Hadjichristidis, Nikos


Book ID
120448167
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
113 KB
Volume
33
Category
Article
ISSN
0024-9297

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Trapping of photogenerated group IV radi
✍ W. G. Skene; Terrence J. Connolly; J. C. Scaiano πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 103 KB πŸ‘ 1 views

A series of trialkyl and triaryl organometallic radicals from group IV generated by hydrogen abstraction by tert-butoxyl radical from the parent hydrides have been examined using laser flash photolysis. The rate constants for the trapping of the metal-centered radicals by the persistent radical TEMP