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Complex I: A Chimaera of a Redox and Conformation-Driven Proton Pump?

✍ Scribed by Thorsten Friedrich

Book ID
110294688
Publisher
Springer US
Year
2001
Tongue
English
Weight
396 KB
Volume
33
Category
Article
ISSN
0145-479X

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📜 SIMILAR VOLUMES

Could Redox-Switched Binding of a Redox-
Could Redox-Switched Binding of a Redox-Active Ligand to a Copper(II) Centre Drive a Conformational Proton Pump Gate? A Synthetic Model Study
✍ Zhicong He; Stephen B. Colbran; Donald C. Craig 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 451 KB

## Abstract A proposal for a redox‐linked conformational gate to proton translocation—a proton pump gate—based upon a transition‐metal redox‐switchable hemilabile ligand (RHL) system is made. Consideration of the requirements for such a system reveals copper(II) to be the ideal metal centre. To tes