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Complex formation of zinc-containing metalloporphyrins and nucleophilic substitution reactions involving pyridines

✍ Scribed by V. P. Andreev, P. S. Sobolev, E. A. Larkina, E. P. Tkachevskaya


Book ID
113063792
Publisher
Springer US
Year
2012
Tongue
English
Weight
389 KB
Volume
48
Category
Article
ISSN
0009-3122

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Formation of ternary complexes involving
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## Abstract Metal ions such as Zn^2+^ and Cu^2+^ can mediate interactions between copolypeptides (Glu~__x__~, Tyr~__y__~)~__n__~ and polynucleotides. CD data show that these ternary complexes are characterized by an unstacking of nucleic acid bases, while the polypeptide adopts an α‐helical conform