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Complex formation in concentrated sulfuric acid between selenium(iv) and 1,1'-dianthrimide

โœ Scribed by F.J. Langmyhr; J.A. Myhrstad


Publisher
Elsevier Science
Year
1966
Tongue
English
Weight
595 KB
Volume
35
Category
Article
ISSN
0003-2670

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Generation of new dithia dications from
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Dithicdibenzothiophenes 2 were prepared by ring contraction of 46dithiothianthrene-S-oxides with n-butyllithium. Both compounds 2 and their monooxides 3 upon dissolution in cont. H2SO4 afforded the corresponding new dithia dications. Electrochemical oxidation of 2 provides the evidence for the neigh