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Complex formation by a stable radical with various unsaturated compounds

โœ Scribed by I. V. Golikov; R. B. Svitych; O. P. Yablonskii

Publisher
SP MAIK Nauka/Interperiodica
Year
1977
Tongue
English
Weight
315 KB
Volume
17
Category
Article
ISSN
0022-4766

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๐Ÿ“œ SIMILAR VOLUMES

Formation of a reasonably stabilized tri
Formation of a reasonably stabilized trichloromethyl anion by the reaction of chloroform with electrogenerated base, and its 1,4-addition to ฮฑ,ฮฒ-unsaturated carbonyl compounds
โœ Tatsuya Shono; Manabu Ishifune; Osamu Ishige; Hiroshi Uyama; Shigenori Kashimura ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 260 KB

A reasonably stabilized trichloromethyl anion (TCMA) was formed by the reaction of chloroform with an electrogenerated base prepared by the electroreduction of Zpyrrolidone, and the addition of this TCIvIA to a$unsaturated esters gave the corresponding B-trichloromethyl esters in good yields.