Transient gratir~ optical Kerr e&t measurements in the isotropic pbase of the nematic liquid crystal pentylcyanobiphenyl (5CB) are presented. Subpicosecond time resolution permits the first direct investigation of the time correlation function for the local mokcular dynamics of the molecules within
Complex dynamics and the stimulated gain spectrum of pentylcyanobiphenyl in the isotropic phase
β Scribed by Rebecca S. Miller; Richard A. MacPhail
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 558 KB
- Volume
- 241
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
We have measured high resolution polarized and depolarized stimulated gain spectra of the liquid crystal pentylcyanobiphenyl (5CB) in its isotropic phase between 36.2 and 122Β°C. Spectral features associated with slow collective reorientation, acoustic waves (Brillouin peaks), and rapid anisotropy fluctuations are all present and can he simultaneously measured with high resolution in a single spectrum. Our results for both the slow and intermediate timescale rcoirientational dynamics are in good agreement with recent transient-grating optical Kerr effect measurements on 5CB.
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From the free jet millimeter-wave spectra of four isotopomers of the weakly bonded oxiraneβ’ β’ β’Kr complex, information on the equilibrium conformation, dynamics, and dissociation energy has been deduced. A C s symmetry is found for the complex, with Kr lying in the Ο v plane of symmetry of oxirane.