The structural positions of protons in lithium niobate crystals (congruent nominally pure, MgO-doped and MgO and Fe 2 O 3 co-doped LiNbO 3 ) have been determined by 1 H nuclear magnetic resonance measurement. Among various possible oxygen triangle positions, the calculation of second moment based on
Complex capacitance in the representation of modulus of the lithium niobate crystals
โ Scribed by Mohammad A. Alim; A.K. Batra; Sudip Bhattacharjee; M.D. Aggarwal
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 335 KB
- Volume
- 406
- Category
- Article
- ISSN
- 0921-4526
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โฆ Synopsis
The lithium niobate (LiNbO 3 or LN) single crystal is grown in-house. The ac small-signal electrical characterization is conducted over a temperature range 35 r Tr 150 1C as a function of measurement frequency (10 rf r 10 6 Hz). Meaningful observation is noted only in a narrow temperature range 59r T r73 1C. These electrical data when analyzed via complex plane formalisms revealed single semicircular relaxation both in the complex capacitance (C n ) and in the modulus (M n ) planes. The physical meaning of this kind of observation is obtained on identifying the relaxation type, and then incorporating respective equivalent circuit model. The simplistic non-blocking nature of the equivalent circuit model obtained via M n -plane is established as the lumped relaxation is identified in the C n -plane. The feature of the eventual equivalent circuit model allows non-blocking aspect for the LN crystal attributing to the presence of the operative dc conduction process. Identification of this leakage dc conduction via C n -plane is portrayed in the M n -plane where the blocking nature is removed. The interacting interpretation between these two complex planes is successfully presented.
๐ SIMILAR VOLUMES
Raman spectra of a series of MgO-doped congruent LiNbO, crystals were obtained with MgO concentrations up to 30 mole%. Single crystals were successfully grown and no precipitates were discovered. The intensity, frequency and line width of the Raman phonons were studied as a function of doping percen