The trimethylsilyl enol ether of (3,5-heptadien-2-one) tricarbonyliron 1 undergoes a highly stereoselective cross aldol reaction with TiCl4-coordinated I]-o.methoxybenzyloxypropanal yielding after deprotection the ketodiol complex 9. Direct decomplexation or decomplexation after totally metal induce
✦ LIBER ✦
Complex Aldol Reactions for the Construction of Dense Polyol Stereoarrays: Synthesis of the C33—C36 Region of Aflastatin A.
✍ Scribed by David A. Evans; Frank Glorius; Jason D. Burch
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 14 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Aldol condensation reactions of chiral (
✍
Michel Franck-Neumann; Paul Bissinger; Philippe Geoffroy
📂
Article
📅
1997
🏛
Elsevier Science
🌐
French
⚖ 250 KB
ChemInform Abstract: Aldol Condensation
✍
M. FRANCK-NEUMANN; P. BISSINGER; P. GEOFFROY
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 32 KB
👁 1 views
ChemInform Abstract: Chelation-Assisted
✍
Tien-Yau Luh; et al. et al.
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 37 KB
👁 2 views
Chelation-Assisted Regioselective C-O Bond Cleavage Reactions of Acetals by Grignard Reagents. A General Procedure for the Regioselective Synthesis of Protected Polyols Having One Free Hydroxy Group. -On treatment with Grignard reagents, acetals containing a neighboring heteroatom (N,O) undergo reg
ChemInform Abstract: Synthetic Studies o
✍
K. HORITA; S. HACHIYA; T. YAMAZAKI; T. NAITOU; J. UENISHI; O. YONEMITSU
📂
Article
📅
2010
🏛
John Wiley and Sons
⚖ 46 KB
👁 2 views