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Completely Diastereoselective Tricarbonyliron Complexation Reactions of Chiral Dienes

✍ Scribed by Tsai, Ming-Shan; Rao, U. Narasimha; Hsueh, Peng-Yu; Yeh, Ming Chang P.

Book ID
118021517
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
103 KB
Volume
20
Category
Article
ISSN
0276-7333

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The (Ξ· 4 -1-azabuta-1,3-diene)tricarbonyliron complexes 10 spectroscopy, as well as X-ray crystallography of 10b, 10c, and 10l. Using variable temperature 13 C-NMR spectroscopy are easily prepared in high yield by condensation of the corresponding arylamines 7 with the cinnamaldehydes 8 and the flux