Complete Regioselection in Palladium-Catalyzed Arylation and Alkenylation of Allylic Alcohols with Hypervalent Iodonium Salts
โ Scribed by Kang, Suk-Ku; Lee, Hong-Woo; Jang, Su-Bum; Kim, Tae-Hyun; Pyun, Sung-Jae
- Book ID
- 119956707
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 153 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
The polymer-bound palladium-catalyzed cross-coupling reaction of allylic alcohols with hypervalent iodomum salts to form carbun-ca~n bonds was achieved at room temperature under extremely mild and aqueous conditions even in the absence of base with very high activity in the Stille coupling reaction.
Pd(O)-catal)zed a~,lation of the aryl-substituted a-allenic alcohols with ,~vpen, alent iodonium salts afforded substituted trans-epoxides Alternatively. arylation ~[ the alkyl-substituted a-a/lenic alcohols in the presence of K2COj afforded syn-d~ol cyclic carbonates and trans-epoxides in the