Obtaining unknown NMR parameters from experimental spectra of exchanging systems is, from a mathematical point of view, associated with the solution of an inverse problem. Inverse problems are usually solved by iterative procedures and calculations may not always converge and the solutions are rarel
✦ LIBER ✦
Complete PMR analysis of naphthalene as an eight spin system
✍ Scribed by R. W. Crecely; J. H. Goldstein
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 302 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The PMR spectrum of naphthalene has been completely analyzed as an eight‐spin system for the first time. It was found that inter‐ring long‐range couplings exist between all combinations of the α and β protons on adjacent rings. The signs and magnitudes of the coupling values have been determined and compared to couplings reported in the literature for other polynuclear compounds.
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