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Complete diastereocontrol in [3+2] cycloaddition reactions: Synthesis of enantiomerically pure fluoromethyl substituted β-amino acids

✍ Scribed by Alberto Arnone; Francesca Blasco; Giuseppe Resnati

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 374 KB
Volume: 53
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(97)10199-5

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✦ Synopsis

The intramolecular reaction of nitrones of crotonic and cmnamic esters of (,S)-3-fluoro-2hydroxypropanal afforded corresponding cycloadducts in good chemical yields and complete stereoselection

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