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Complete carbon-13 and proton NMR assignments for two mesogenic series containing cyclohexyl rings

✍ Scribed by Cheryl Baldwin Frech; B. M. Fung; Martin Schadt


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
270 KB
Volume
26
Category
Article
ISSN
0749-1581

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✦ Synopsis


Complete ' 3C and ' H spectral assignments for two series of liquid crystals in CDCI, solution were made. The 4-(trans-4- alkylcyclohexyl)benzonitriles had propylto pentyl-substituted alkyl chains, whereas the 4-(trans-4-alkenylcyclohexyl) benzonitriles had varying positions of the alkenyl bond. "C and 'H chemical shifts and 13C-' H scalar coupling constants are reported. KEYWORDS 'H NMR 13C NMR 2D NMR Liquid crystals 4-(trans-4-Alkylcyclohexyl)benzonitriles 4-(trans-4-Alkenylcyclohexyl) benzonitriles K E Y W O R D S 1 5 N NMR Wyosine INEPT N,H coupling constants 15N chemical shifts


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## Abstract Complete ^13^C and ^1^H NMR spectral assignments for a series of derivatives of the naturally occurring C‐ring aromatic diterpene resin acid dehydroabietic acid have been made. The use of a combination of 1D and 2D NMR techniques allowed mostly unambiguous assignments of all ^13^C reson