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Complementarity of universal calibration SEC and 13C NMR in determining the branching state of polyethylene

✍ Scribed by André M. Striegel; Michael R. Krejsa


Book ID
101352612
Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
283 KB
Volume
38
Category
Article
ISSN
0887-6266

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The effect of an unsymmetric branched br
✍ Antoni Jurkiewicz; Nancy W. Eilerts; Eric T. Hsieh 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 100 KB 👁 2 views

The 13 C NMR spectra of copolymers of ethylene with 4-methyl-1-hexene and 4-methyl-1-pentene, respectively, were compared. The 4-methyl-1-hexene/ethylene copolymer, which contains an unsymmetric 2-methylbutyl branch, exhibits two distinct 13 C NMR peaks for each of the pairwise methylenes spaced one