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Competitive self-assembly and electrochemistry of some ferrocenyl-n-alkanethiol derivatives on gold

✍ Scribed by Stephen E. Creager; Gary K. Rowe

Publisher
Elsevier
Year
1994
Tongue
English
Weight
845 KB
Volume
370
Category
Article
ISSN
1572-6657

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Long-chain alkanethiols I R(CH,),SH] and substituted phenylthioureas (RPhNHCSNH,) adsorb from solutions on the surface of gold. Analysis by XPS indicates that the binding energies of the S 2p and Au 4d, peaks in alkanethiol monolayers are 162.3 and 335.4 eV, which are 1.4 and 0.4 eV higher than thos