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Competitive Photochemical Pathways in the Rearrangement of Tetrasubstituted 4H-Thiopyrans

✍ Scribed by Hooshang Pirelahi; Assieh Atarodiekashani; Seyyedmajid Seyyedmoossavi; Hossein Daryanavardedargahani


Book ID
106213364
Publisher
Springer Vienna
Year
2004
Tongue
English
Weight
87 KB
Volume
135
Category
Article
ISSN
0026-9247

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Competitive pathways in the thermal rear
✍ FranΓ§oise Bourelle-Wargnier; Marcel Vincent; Josselin Chuche πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 216 KB

R ?a-d 6 3\_d-f + , 1 -?/. R" +d,e RI'= nPr 16 R"= Me Scheme 1 We report here our investigations on the thermal isomerization of cis-2-ethynyl-3vinyloxiranes Lb-f substituted at C-2 by an alkyl group. Our new results lend support to the proposed mechanism and bring a new insight into the reactivity