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Competitive bridgehead substitution in electrophilic oxidation reactions of ethanoadamantane

โœ Scribed by Sosnowski, James J.; Murray, Roger K.

Book ID
126979322
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
403 KB
Volume
49
Category
Article
ISSN
0022-3263

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โœ Glen A. Russell; K.L. Nagpal ๐Ÿ“‚ Article ๐Ÿ“… 1961 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 171 KB

THE metal halide-catalyzed disproportionation of substituted tetraalkyl-2 RSi(CH3)3 A12Br6+ Si(CH3)4 + R2Si(CH3)2 silanes is considered to involve electrophilic substitution on carbon and nucleophilic substitution on silicon. 2 The transition state is pictured as: We have measured the initial rate