Competition of monomolecular and bimolecular reactions of the alkyl radicals of artemisinin
β Scribed by S. L. Solodova; E. T. Denisov
- Book ID
- 110170833
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 210 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0023-1584
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π SIMILAR VOLUMES
## Abstract An exact collision theory of unimolecular and bimolecular gas phase reactions is derived from a general quantumβmechanical formulation of reactions rates based on the assumption that the reactants are in thermal equilibrium. In this way the quantum corrections to the classical collision
The rate wnstants of selfxactions of ketyl radicals of acetophenone in n-heptane [2k = (3.2 2 05) x 109 hl-1 s-t] and diphenylaminyl radicals in toluene [2k = (3.3 f 05) x lo7 11-t s-l ] hat= been determined at 298 K using the flash photolysis technique-The rate constant of ketyl radicals is equal t