Competition of concatenated and thermally activated medium reorganization in photoinduced electron transfer reactions
β Scribed by M. G. Kuzmin; I. V. Soboleva; E. V. Dolotova
- Book ID
- 110164514
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2006
- Tongue
- English
- Weight
- 256 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0018-1439
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Laser-flash-photolysis experiments show that, in MeCN at 20". perylene (P) undergoes three distinct electrontransfer reactions: a) IP\* + MeCN 4 P'+ + MeCN'b) ' P \* t P 4 P ' + + P ' c) 3P\* + 3P\* 4 (P.P)\* ~ P" + P' These processes originate probably from the thermally relaxed excited states of P
## Abstract Photoinduced electronβtransfer (PET) reactions were investigated for the cyclic oligosilanes and high molecular weight polysilanes in the presence of 9βcyanoanthracene (CA), 9,10βdicyanoanthracene (DCA), and triphenylpyrylium tetrafluoroborate (TPP^+^BF) using chemical and spectroscopic