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Competition in the sodium iodide catalysed isomerisation of some aziridines

✍ Scribed by Ne´ji Besbes

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 96 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)00752-7

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✦ Synopsis

N-Acyl-2,2-dimethylaziridines have been shown to be isomerised by sodium iodide into three isomers. The yield of these isomers appears to depend on the electronic effect of the acyl group.

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ChemInform Abstract: Competition in the

ChemInform Abstract: Competition in the Sodium Iodide Catalyzed Isomerization of Some Aziridines.

✍ N. BESBES 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 26 KB 👁 1 views

The methylation of some phenols and alco

The methylation of some phenols and alcohols with sodium hydride / methyl iodide in tetrahydrofuran at room temperature

✍ Barbara A. Stoochnoff; N.Leo Benoiton 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 160 KB

Alcohols and weakly acidic phenols which do not react with diazomethane can be methylated in the presence of acid catalysts 2.3 , but certain hindered alcohols 2,3 and phenols 3 react with difficulty or not at all. We describe here the use of sodium hydride / methyl iodide in tetrahydrofuran (THF) a