Competition in reactions of the CF3radical with oxygen and fluorine
β Scribed by V. I. Vedeneev; M. A. Teitel'boim; A. A. Shoikhet
- Book ID
- 112493664
- Publisher
- Springer
- Year
- 1977
- Tongue
- English
- Weight
- 234 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
## Abstract The relative rate technique has been used to determine the rate constants of the reactions of OH radicals with CF~3~CClο£ΎCCl~2~ (__k__~1~), CF~3~CClο£ΎCClCF~3~ (__k__~2~) and CF~3~CFο£ΎCFCF~3~ (__k__~3~). Experiments were carried out at (298Β±2) K and atmospheric pressure using ultrapure nitr
Hydrogen abstraction from boron trimethyl has been studied using the abstracting radicals CF3 and CD3, from the photolysis of the corresponding ketones over the temperature range of 150Β° to 300Β°C. The following Arrhenius parameters were obtained: 98 kcal/mole (CFJ + BMe3); log A = 11.6, E = 6.59 kc