✦ LIBER ✦

Competition between HF And HCl molecular elimination in IRMPD of 1,2-dichloro-1,2-difluoroethane

✍ Scribed by Yo-ichi Ishikawa; Shigeyoshi Arai

Book ID: 103019863
Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 470 KB
Volume: 103
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)87075-4

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✦ Synopsis

The infrared multiple-photon decomposition of 1,2-d1chloro-1.2difluoroethane has been studled using time-resolved infrared ermssion. Vibratlonally excited parent molecules dlssoclate competitively via two channels to form viirat~onally excited HCI and HF. dependtng strongly on CO2 iaser fluence. The yield of HF elimination increases with fiucnce. while that of HCI elimination reaches a plateau and then decreases. Volume 103. number 1 CHEMICAL PHYSICS LETTERS

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