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Competition between Geminate Recombination and Reaction with a Macromolecule

✍ Scribed by Bolton, Charlotte E.; Green, Nicholas J. B.; Harris, Rachel; Pimblott, Simon M.


Book ID
125996897
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
132 KB
Volume
102
Category
Article
ISSN
1089-5639

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## Abstract The photolysis of (R)‐(+)‐phenyl and (R)‐(+)‐__p__‐anisyl 1, 2, 3‐trimethylcyclopent‐2‐enyl ketone (**1**, **2**) and the corresponding __rac__‐1‐ and 3‐desmethyl analogs (**3**, **4**) led to isomerization due to formal 1, 3 aroyl migration and to formation of aryl aldehydes (**7**, **