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Competition Between Bulk and Surface Pathways in Mixed Ionic Electronic Conducting Oxygen Electrodes

โœ Scribed by Coffey, Gregory W.; Pederson, Larry R.; Rieke, Peter C.

Book ID
125961732
Publisher
The Electrochemical Society
Year
2003
Tongue
English
Weight
205 KB
Volume
150
Category
Article
ISSN
0013-4651

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๐Ÿ“œ SIMILAR VOLUMES

Oxygen interaction of CdS-based gas sens
Oxygen interaction of CdS-based gas sensors with different stoichiometric compositions was studied by X-ray photoelectron spectroscopy (XPS) and thermal-desorption mass spectroscopy observations combined with conductivity measurements. Three different types of film with different atomic ratios of Cd/S were used in the study of oxygen chemisorption in a low-temperature range between 300 and 570 K. Spray pyrolysis was used for the deposition of the films on glass substrates; XPS and energy dispersive spectroscopy of X-ray together with atomic force microscopy and scanning electron microscopy were used for the characterization of the composition and structure of the films. It was possible to distinguish different temperature ranges for the thermal desorption of the different adsorbed oxygen species. A comparison of the data from XPS and mass-spectroscopy observations with conductance measurements allows to conclude that metallic surface atoms are responsible for different interactions of oxygen species with CdS surfaces.
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