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Competing Diels—Alder Reactions of Activated Nitroethylene Derivatives and [3,3]-Sigmatropic Rearrangements of the Cycloadducts.

✍ Scribed by Peter A. Wade; James K. Murray Jr.; Sharmila Shah-Patel; Hung T. Le


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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Pericyclic Reaction Behavior of Cyclopentadienones Toward Acyclic Conjugated Dienes. [3,3]-Sigmatropic Rearrangement and Double Diels-Alder Reactions of the endo[4 + 2]π Cycloadducts. -The Diels-Alder reaction of cyclopentadienone (I) with acyclic conjugated dienes (II) leads to the expected endo-p