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Comparison of two linear approximations to vibronic coupling

✍ Scribed by Marek Z. Zgierski; Alvin P. Penner

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
247 KB
Volume
45
Category
Article
ISSN
0009-2614

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✦ Synopsis

Two commonly used linear approximations for vibronic coupling in molecules are mvestigated. It is shown that one leads to physically unacceptable potentials if the coupling is not evtrcmely weak while the other leads to well-behaved, but anharmonic, adiabatic potentials.

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