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Comparison of time-resolved fluorescence Stokes shift measurements to a molecular theory of solvation dynamics

โœ Scribed by Maroncelli, Mark; Fleming, Graham R.


Book ID
120303151
Publisher
American Institute of Physics
Year
1988
Tongue
English
Weight
857 KB
Volume
89
Category
Article
ISSN
0021-9606

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The time-resolved fluorescence Stokes shift of trans-4-dimethylamino-4'-cyanostilbene has been measured as a function of temperature in polar solvents. Fluorescence spectra were found to exhibit exponential rise times of 80 to 640 ps between 297 and 250 K. These observations are attributed to two in