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Comparison of thick film capillaries with packed columns from the point of view of loadability in combination with high resolving power

✍ Scribed by Ghijsen, R. T. ;Poppe, H.


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
542 KB
Volume
11
Category
Article
ISSN
0935-6304

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✦ Synopsis


The present paper compares the potential of high pressure packed column gas chromatography, with a particle size in the range of 30-80 I m and conventional packed column GC, with that of thick film capillaries for obtaining the maximum loadability at a given performance in efficiency and speed of separation. An alternative treatment, discussing the maximum efficiency of the three column types at normalized loadability and speed of separation is given. Known and established relationships describing plate height, loadability, and linear velocity are used to arrive at the said comparisons. The conclusion of the paper indicates a reconsideration of packed column GC for particular types of analyses where large amounts or high concentrations are required in the detection step.