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Comparison of the Surprising Metal-Ion-Binding Properties of 5- and 6-Uracilmethylphosphonate (5Umpa2− and 6Umpa2−) in Aqueous Solution and Crystal Structures of the Dimethyl and Di(isopropyl) Esters of H2(6Umpa)

✍ Scribed by Eva Freisinger; Rolf Griesser; Bernhard Lippert; Cristóbal F. Moreno-Luque; Juan Niclós-Gutiérrez; Justyn Ochocki; Bert P. Operschall; Helmut Sigel


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
456 KB
Volume
14
Category
Article
ISSN
0947-6539

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✍ P. Becker; P. Held; L. Bohatý 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB 👁 2 views

Large single crystals of the polar, hydrated pentaborates Me[B 5 O 6 (OH) 4 ]•2H 2 O (Me = Rb, NH 4 ) were grown from aqueous solutions. The structure of NH 4 [B 5 O 6 (OH) 4 ]•2H 2 O was redetermined and proved to be orthorhombic (space group Aba2 (No. 41) with a = 11.3192(7) Å, b = 11.0261(8) Å, c