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Comparison of the structural and rheological consequences of micelle formation in solutions of a model di-block copolymer

โœ Scribed by J.S. Higgins; S. Blake; P.E. Tomlins; S.B. Ross-Murphy; E. Staples; J. Penfold; J.V. Dawkins

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
902 KB
Volume
29
Category
Article
ISSN
0032-3861

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Abstraet--A calorimetric study was made of micelle formation by a polystyrene-b-polyisoprene block copolymer in n-hexadecane which is a selectively bad solvent for polystyrene. A value of -44.0 + 4.0 kJ mol-~ was obtained for the enthalpy of micellisation, in good agreement with a value of -40.7 +2.