Comparison of the Reactivities of Dimethylsilylene (SiMe 2 ) and Diphenylsilylene (SiPh 2 ) in Solution by Laser Flash Photolysis Methods
β Scribed by Moiseev, Andrey G.; Leigh, William J.
- Book ID
- 120514567
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 441 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0276-7333
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The reaction mechanism in the UV photochemistry of 2-chloro-2'-deoxyadenosine (Cladibrine) and 2-bromo-2'-deoxyadenosine in aqueous solution has been studied by laser photolysis at nanosecond time resolution. It is found that excitation at 266 nm wavelength produces heterolytic cleavage of the halog