## Abstract Improving the conductivity of electrospinning solutions is often achieved by adding small amounts of conductive additives. HMIMCl, a room temperature ionic liquid, and TEBAC, a quaternary ammonium salt, were added to polylactic acid in chloroform and their effects on solution properties
Comparison of the Effects of an Ionic Liquid and Other Salts on the Properties of Electrospun Fibers, 2 – Poly(vinyl alcohol)
✍ Scribed by Ganesh Kumar Arumugam; Sourabh Khan; Patricia A. Heiden
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 992 KB
- Volume
- 294
- Category
- Article
- ISSN
- 1438-7492
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✦ Synopsis
Abstract
Understanding the effect of conductivity in electrospinning solutions is crucial in order to improve or control the electrospinning process. In this paper the effect of adding small amounts (0.039–0.259 mol · kg^−1^) of three different conductive additives to aqueous solutions of polyvinyl alcohol has been investigated. The salts were HMICl (a room temperature ionic liquid), TEBAC (a quaternary ammonium salt) and KCl. Addition of these salts caused a steady increase in the solution conductivity but the fiber diameter was typically greater than that of PVA alone, and exhibited an oscillatory trend. The oscillatory trend on the fiber diameter is attributed to fiber backbuilding and fusion that occurs prior to deposition on the collector.
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## Abstract A proton‐exchange membrane for a direct methanol fuel cell was prepared by modifying the chemical structure of poly(vinyl alcohol) (PVA) via a sulfonation. The sulfonation was carried out by using sulfophthalic acid (sPTA) as a sulfonating agent. The sulfonated PVA membranes, with a var