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Comparison of the crystal structures of alkaline (M = Li,Na,K,Rb,Cs) and pseudo-alkaline (M = NO,NH4) tetrachloroaluminates, MAlCl4

โœ Scribed by Mairesse, G. ;Barbier, P. ;Wignacourt, J.-P.


Book ID
118689973
Publisher
International Union of Crystallography
Year
1979
Weight
834 KB
Volume
35
Category
Article
ISSN
0567-7408

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Blue crystals of metal nitratocuprates(II), M 3 [Cu(NO 3 ) 4 ](NO 3 ) (M = K (I), NH 4 (II), Rb (III)) and Cs 2 [Cu(NO 3 ) 4 ] (IV) were synthesized from Cu(NO 3 ) 2 3 H 2 O and MNO 3 by heating at 100ยฑ140 ยฐC during 3ยฑ12 h. X-ray single crystal structures for isotypic I and II reveal the presence of