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Comparison of the addition of bromine chloride to 1-hexene and 1-hexyne in carbon tetrachloride and methanol

✍ Scribed by Heasley, Victor L.; Shellhamer, Dale F.; Iskikian, John A.; Street, David L.; Heasley, Gene E.

Book ID
126826499
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
511 KB
Volume
43
Category
Article
ISSN
0022-3263

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## Abstract The Pd‐catalyzed addition of carbon monoxide and carbon tetrachloride to 1‐octene gave coadduct [alkyl 2‐(2, 2, 2‐trichloroethyl)octanoate] as the major product in supercritical carbon dioxide by using pyridine as the base. It was found that the selectivity and the yield of coadduct wer