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Comparison of Perturbative and Variational Treatments of Molecular Vibrations: Application to the Vibrational Spectrum of HFCO up to 8000 cm -1†

✍ Scribed by Iung, Christophe; Ribeiro, Fabienne; Sibert, Edwin L.


Book ID
121401172
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
432 KB
Volume
110
Category
Article
ISSN
1089-5639

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Vibrational Assignment and Anharmonic Re
✍ Jason C. Crane; Akio Kawai; Hakhyun Nam; Horst Clauberg; Harry P. Beal; Penny Gu 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 331 KB

states of S 1 are presented up to 9000 cm 01 . Progressions are assigned primarily to vibrational states with excitation in the Franck-Condon active modes n 2 , n 5 , and n 6 . The spectrum is perturbed by a 266 (n 2 É 2n 6 ), a 233 (n 2 É 2n 3 ), and a 3566 (n 3 / n 5 É 2n 6 ) anharmonic resonance.