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Comparison of Metallic Chlorides as Catalysts for the Friedel—Crafts Ketone Synthesis 1,2

✍ Scribed by Dermer, O. C.; Wilson, David M.; Johnson, F. M.; Dermer, V. H.


Book ID
126165660
Publisher
American Chemical Society
Year
1941
Tongue
English
Weight
339 KB
Volume
63
Category
Article
ISSN
0002-7863

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MCM-41 type molecular sieves as catalyst
✍ Eric A. Gunnewegh; Saritha S. Gopie; Herman van Bekkum 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 660 KB

Molecular sieves of the MCM-41 type were studied as catalysts for the Friedel-Crafts acylation of 2-methoxynaphthalene in the liquid phase. When MCM-41 in the H+ form is used as Bronsted-acid catalyst, acylation with acetic anhydride gives substitution predominantly at the l-position. Increased reac