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Comparison of metal-metal bond energies in the chromium(II) and copper(II) acetate dimers

✍ Scribed by Cannon, Roderick D.

Book ID
120433476
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
283 KB
Volume
20
Category
Article
ISSN
0020-1669

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The dlfference between the metal-metal 6 and TT orbItal lonlzation energws for the complexes M~(OZCCF&, M2(02CCH3)4, M2(CaHsf.+\_ and Mz(hlHP)1, (where M = Cr or MO and H{MHP)= 6-methyl-2-hydrouypyrtdme) mcreases, wtthm each series. as the metal-metal bond length decreases. The vanahon m the metal-m