A novel approach to the preparation and monitoring of molecules in high vibrational levels in their electronic ground state is presented. An ultrashort laser pulse prepares a well defined wavepacket in the electronic excited state and, following the evolution of this wavepacket, the proper frequency
โฆ LIBER โฆ
Comparison of ground- and excited-state raman transitions using resonant coherent stokes generation
โ Scribed by J.R. Andrews; R.M. Hochstrasser
- Book ID
- 103019743
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 474 KB
- Volume
- 83
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Coherent Stohes generation was explored as a means to inveshgate vibrational dephasmg m both the ground stztte and fist exnted smglet state of pentacene m benzo~c aad. The dephasmg-mdticed coherent enussion (DICE) was used to obtam the ground-and euntcd-state Rams linewldths between 1.6 K and 200 K. The broadenlng for both modes displayed an Arrhenmsenerfy of ==lOO cm-'.
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