Charge-transfer reactions of Ar+ with CH,Cl,\_, (n= l-3) at thermal energy have been studied by using a flowing-afterglow apparatus coupled with a low pressure chamber. Dissociative charge-transfer leading to CH: (91 k 5%) CH&l+ (95 k 2%), and Ccl+ (69 f 3%) are major product channels for CH,Cl, CH#
Comparison of energy partitioning in Ar+ and N2+ charge-transfer reactions
✍ Scribed by Denise C. Parent; Renée Derai; Gérard Mauclaire; Michel Heninger; Rose Marx; Marina E. Rincon; Anthony O'Keefe; Michael T. Bowers
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 501 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The km&c energy released in near-thermal charge-transfer reactions of Ar* and NC with NO, 0,. CO, H,O, N,O. CO, and NH, has been measured. The partitioning between kinetic and inlemal modes is found lo be very similar for mosl 01 the Ar+/N: pan-s. Tko hypotheses LO explain tis similarity are proposed and discussed.
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The O:-Ar charge-transfer reactions have been investigated for both the XzllS and a4n, states of 0: in the kinetic energy range of 0.7 to 3.0 keV. Exhibited resonant and non-resonant behavior of the cross sections is consistent with theoretical predictions. ## Vohme ,24, number 3 CHEMICAL PHYSICS