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Comparison of Chiral and Racemic Forms of Zinc Cyclohexane trans-1,2-Dicarboxylate Frameworks: A Structural, Computational, and Calorimetric Study

✍ Scribed by Andrew J. Bailey; Clare Lee; Russell K. Feller; James B. Orton; Caroline Mellot-Draznieks; Ben Slater; William T. A. Harrison; P. Simoncic; A. Navrotsky; Martin C. Grossel; Anthony K. Cheetham


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
578 KB
Volume
120
Category
Article
ISSN
0044-8249

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Chiral diamines. Part 3: Effect of ligan
✍ Kenneth B. Wiberg; William F. Bailey 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 320 KB

The deprotonation N-Boc-pyrrolidine by i-PrLi-(S,S)-1,2-bis(N,N-dimethylamino)cyclohexane has been studied at the HF/3-21G and B3P86/6-31G\* theoretical levels. The two lowest energy complexes of the N-Boc-pyrrolidine-i-PrLi-diamine ligand, as well as the transition states leading to proton transfer